In naming ionic compounds, there are some rules. The first rule is proposed for ionic compounds which have a single cation and a single anion, so this compound consists of 2 different elements, metal and non metal. This compound can be grouped as a binary ionic compound. There is a different binary compound, i.e. a covalent compound.
Binary Compounds of Cations with a single charge.
Given Formula, Write the NameIn your textbook there is a table contains list of cations and anions.
1. Na+ and Cl- forms NaCl, sodium chloride
2. Na+ and O2- forms Na2O, sodium oxide
3. Al3+ and F- forms AlF3, aluminium fluoride
Please remember that all elements involved in the compounds have ONLY ONE charge. It includes both the cation and the anion involved in the formula.
The order for naming a binary compound is first the cation, then the anion.
Use the name of cation with a fixed charge directly from the periodic table.
The name of the anion will be made from the root of the element's name plus the suffix "-ide."
Given Name, Write the FormulaThe order for writing a formula is first the cation, then the anion.
You have to know the charges of each cation and anion.
The sum of the positive charge and the sum of the negative charges must add up to zero, because compound is neutral.
You may adjust the subscripts to get a total charge of zero. Don't change the charge of each ion.
1. Potassium sulfide, K2S
2. Barium bromide, BaBr2
Binary Compounds of Cations with Variable ChargesGiven Formula, Write the Name The cations involved at least have 2 charges. In your texbook there is a list of cations with variable charges. For example : Cu +1 and +2; Fe +2 and +3; Hg +1 and +2; Pb +2 and +4; Sn +2 and +4; Au +1 and +3.
1. FeCl2, Iron(II) chloride
2. Cu2O, Copper(I) oxide
Polyatomic CompoundsThere are polyatomic cations and anions. This compound consists of monoatomic cation and polyatomic anion or polyatomic cation and monoatomic anion or both cation and anion are polyatomic.
1. K2SO4, Potassium sulphate
2. (NH4)2S, Ammonium sulfide
3. NH4NO2 Ammonium nitrite